The crystal structure of (<i>E</i>)-3-chloro-2-(2-(4-fluorobenzylidene)hydrazinyl)pyridine, C<sub>12</sub>H<sub>9</sub>Cl<sub>F</sub>N<sub>3</sub>
نویسندگان
چکیده
Abstract C 12 H 9 Cl F N 3 , monoclinic, P 2 1 / n (no. 14), a = 10.120(4) Å, b 13.823(6) c 16.480(7) β 91.744(8)°, V 2304.4(17) Å Z 8, R gt ( ) 0.0402, wR ref 0.0932, T 113.15 K.
منابع مشابه
Crystal Structure of Schiff base Compound 2-[(2-chloro-4-nitrophenyl) iminomethyl] phenol
Single crystals of Schiff base compound 2-[(2-chloro-4-nitrophenyl) iminomethyl] phenol (1) were grown by the slow evaporation technique at room temperature. The crystal structure of the title compound was determined by single crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group P21, with two symmetry independent molecules. Intramolecular O-H···N hydr...
متن کاملCrystal structure of 2-(4-chloro-3-fluorophenyl)-1H-benzimidazole
In the title compound, C13H8ClFN2, the dihedral angle between the plane of the benzimidazole ring system (r.m.s. deviation = 0.022 Å) and the benzene ring is 26.90 (8)°. The F atom at the meta position of the benzene ring is disordered over two sites in a 0.843 (4):0.157 (4) ratio. In the crystal, mol-ecules are linked by N-H⋯N hydrogen bonds, forming infinite C(4) chains propagating along [010...
متن کاملCrystal structure of 4-chloro-2-iodoaniline
In the crystal structure of the title compound, C6H5ClIN, the amino group engages in N-H⋯N hydrogen bonding, creating [100] chains. A Cl⋯I contact is observed [3.7850 (16) Å]. The parallel planes of neigbouring mol-ecules reveal highly offset π-stacking characterized by a centroid-centroid distance of 4.154 (1), a centroid-to-plane distance of 3.553 (3) and ring-offset slippage of 2.151 (6) Å.
متن کاملCrystal structure of 3-bromomethyl-2-chloro-6-(dibromomethyl)quinoline
In the title compound, C11H7Br3ClN, the quinoline ring system is approximately planar (r.m.s. = 0.011 Å). In the crystal, mol-ecules are linked by C-H⋯Br inter-actions forming chains along [10-1]. The chains are linked by C-H⋯π and π-π inter-actions involving inversion-related pyridine rings [inter-centroid distance = 3.608 (4) Å], forming sheets parallel to (10-1). Within the sheets, there are...
متن کاملCrystal structure of ethyl 2-chloro-5,8-dimethoxyquinoline-3-carboxylate
In the title compound, C14H14ClNO4, the dihedral angle between the quinoline ring system (r.m.s. deviation = 0.0142 Å) and ester planes is 18.99 (3)°. The C-O-C-Cm (m = meth-yl) torsion angle is -172.08 (10)°, indicating a trans conformation. In the crystal, the mol-ecules are linked by C-H⋯O and C-H⋯N inter-actions, generating layers lying parallel to (101). Aromatic π-π stacking [centroid-cen...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Zeitschrift Fur Kristallographie-new Crystal Structures
سال: 2022
ISSN: ['2197-4578', '1433-7266']
DOI: https://doi.org/10.1515/ncrs-2021-0489